Scientists uncover new 鈥榠n-between鈥� materials for solar fuels and batteries
Researchers have identified previously unknown materials, including a new form of a widely studied clean-energy material, by carefully controlling and tracking how molecular precursors break down during heating.
Published in , the study uncovers a series of hidden intermediate stages that appear when molecules are heated to become materials. Capturing these intermediates opens a new way to discover and design materials that aren鈥檛 accessible through typical synthetic methods.
Dr Sebastian Pike, Department of Chemistry, University of 糖心TV said: 鈥淲hen materials are made by heating, scientists usually focus on the final product, the 鈥楤鈥� that results from 鈥楢.鈥� But this study shows that there are many fascinating stages in between 鈥楢鈥� and 鈥楤,鈥� and these hidden steps, could be just as important.
鈥淲e didn鈥檛 know exactly what we would find going in, but we were confident there would be something interesting and unknown in the intermediate phases. We were thrilled to discover that some of these could have practical uses, even from the very first experiments.鈥�
Starting with specially designed 鈥榮ingle-source precursors鈥�, molecules containing all the elements needed to create a material, the team tracked how they transformed during heating. This revealed several new material phases, including a previously unknown, kinetically stabilised form of bismuth vanadate (BiVO鈧�) named 尾-BiVO鈧�.
BiVO鈧� is a valuable clean energy material because it has a 鈥渂and gap鈥� (the energy it needs to absorb sunlight and drive chemical reactions) that hits a sweet spot: it absorbs sunlight efficiently while still providing enough energy to split water and produce clean hydrogen fuel.
The newly discovered 尾-BiVO鈧� has a different atomic structure from previously known forms of the material. The new variant has a significantly larger band gap, meaning it interacts with light differently. This could offer new opportunities for tuning the performance of materials used in solar fuel generation, catalysis, and electronics.
The potential applications were not limited to solar fuels. Another of these hidden intermediate materials was found to store large amounts of lithium, suggesting it could be useful for next-generation battery technologies.
Dr Dominik Kubicki, School of Chemistry, University of Birmingham said: 鈥淲hat鈥檚 exciting is that these 鈥榠n-between鈥� materials aren鈥檛 just stepping stones 鈥� they can have useful properties in their own right. By understanding and controlling how they form, we can start to design better materials for batteries, catalysis, and solar energy."
The researchers were able to observe these normally hidden intermediate states by combining state of the art techniques - including solid-state NMR spectroscopy, X-ray diffraction, and pair distribution function analysis.
They also found that the choice of precursor, and how it breaks down, can be used as a powerful tool to control material formation, allowing the team to access structures that are difficult to produce using conventional heating methods.
Dr. Pike concluded: 鈥淲e only studied a few precursors here, but this work points to a broader opportunity in materials science. By carefully controlling temperature, precursor chemistry and reaction pathways, there may be many more 鈥渉idden鈥� but extremely useful materials to be found.鈥�
ENDS
Notes to Editors
The paper, 鈥淎morphous intermediates and discovery of a kinetic polymorph of BiVO4 from heating V+Bi+Zn single-source precursors鈥�, is published by Nature Communications. DOI:
Image adapted from Figure 1 - Hands, A.E., Barnes, T.J., Scarperi, A. et al. Amorphous intermediates and discovery of a kinetic polymorph of BiVO4 from heating V+Bi+Zn single-source precursors. Nat Commun 17, 3739 (2026). DOI:
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