ࡱ> %` $bjbj"x"x .$@@$  g"(JJJJJJJ$h EJJJJJJJ!JJJJJ v4J"70g l  $JJJJJJJ JJJgJJJJ Single pure compound N-Allyl-2-bromo-2-methyl-N-(2-methyl-propenyl)-propionamide  EMBED ISISServer  Pale yellow oil, yield 75%, Rf (9:1 petrol:ethyl acetate) 0.23; umax (film)/cm-1 3079, 2974, 2929, 1637, 1463, 1389, 1365, 1342, 1276, 1180, 1107, 1053, 991, 918, 829, 778, 751, 635; dH (400 MHz, CDCl3) 6.40 (1H, br s), 5.83 (1H, ddt, J 17.3, 10.3, 5.6 Hz), 5.16 (1H, dq, J 17.3, 1.8 Hz), 5.12 (1H, dq, J 10.3, 1.8 Hz), 4.06 (2H, br d, J 5.6 Hz), 1.93 (6H, s), 1.76 (3H, d, J 1.5 Hz), 1.64 (3H, d, J 1.5 Hz); dC (100.6 MHz, CDCl3) 170.3, 134.5, 132.6, 125.8, 116.5, 58.2, 54.1, 32.0, 21.7, 18.6; m/z (FAB) 262 (MH)+, 260 (MH)+, 180, 154, 136; [Found: (MH)+, 260.0636, C11H18NOBr requires (MH)+, 260.0650]; [Found: C, 50.5; H, 7.0; N, 5.3. C11H18NOBr requires C, 50.8; H, 7.0; N, 5.4]. Unseparable mixture of compounds (or rotamers) 2:1 E- and Z-2-bromo-N-(4-methoxy-benzyl)-2-methyl-N-penta-1,3-dienyl-propionamide  EMBED ISISServer  Pale brown oil (41%), Rf (9:1 petrol:ethyl acetate) 0.27; umax (film)/cm-*,  Z \ d v z H J L j l   2 4 0 2 L P R V ^ ` z | 246IJĦėċėĦėĦċċċĦĦĦċĦĦăzhg,phMmCJhMmCJaJhEhMmCJH*aJhEhMmCJOJQJaJhEhMmCJH*aJ#jE hEhMmCJUVaJhEhMmCJaJjhEhMmCJUaJhEhMm56CJaJhMm56CJaJhMmhMm5.*,46<>n"$ $@&a$gdMm $@&a$gdMm $dha$gdMm $dh@&a$gdMm $dh@&a$gdMm$6:<>@fhjlnҶ{k\kLJL\kkUhMmhMmCJH*aJmHsHhg,phMmCJOJQJaJhMmhMmCJH*aJmHsHjhg,phMmCJUaJ#jF hg,phMmCJUVaJhg,phMmCJaJjhg,phMmCJUaJhMmhMmCJaJmHsHhMmCJ\]mHsHhMmhMmCJ\]mHsHhMmhMmCJmHsH hMmCJhMmhMm6aJ1 2933, 2837, 1664 (C=O), 1611, 1513, 1460, 1358, 1299, 1248, 1177, 1111, 1032, 826; dH (400 MHz, CDCl3) 7.61 (0.5 H, d, J 13.1 Hz, Z), 7.53 (1H, d, J 13.8 Hz, E), 7.12 (1H, d, J 8.8 Hz, Z), 7.09 (2H, d, J 8.8 Hz, E), 6.86 (1H, d, J 8.8 Hz, Z), 6.84 (2H, d, J 8.8 Hz, E), 6.06-5.93 (2H, m, E and Z), 5.70 (1H, dd, J 13.8, 10.5 Hz, E), 5.55 (1H, dq, J 13.6, 6.8 Hz, E), 5.42 (0.5H, dq, J 9.5, 6.5 Hz, Z), 4.94 (1H, br s, Z), 4.89 (2H, br s, E), 3.77 (1.5 H, s, Z), 3.76 (3H, s, E), 2.04 (3H, s, Z), 2.03 (6H, s, E), 1.72 (3H, dd, J 6.8, 1.5 Hz, E), 1.62 (1.5 H, br d, J 6.5 Hz, Z); dC (100.6 MHz, CDCl3) 169.1 and 169.0 (E and Z), 158.7 and 158.6 (E and Z), 132.5 (Z), 130.2 (E), 129.1 (E), 129.0 (E and Z), 127.8 (2 x E and Z), 127.1 (Z), 124.7 (Z), 114.5 (E), 114.1 (E and Z), 109.5 (Z), 56.9 (E), 56.8 (Z), 55.2 (E and Z), 49.1 (E and Z), 32.6 (E and Z), 18.2 (E), 13.4 (Z); m/z (FAB) 307, 206, 154, 136, 121.  @BvxDFPR "HJpr@B02FH\^rt~ "$hMmhMmCJH*aJmHsHhg,phMmCJOJQJaJhMmhMmCJaJmHsHhMmhMm6CJaJmHsHL$68LN`bln"$hMmhmHsHhMmhMm6CJaJmHsHhMmhMmCJaJmHsH,1h. A!"#$% Dd b  c $A? ?3"`?2Z}YdCw]D `!Z}YdCw]ӴbHkxcdd``bf``aaV ae~bq31.c8@@ ̂ ed4?Dt#TZɱ(31Í攴7Iх<ҨC]h#573ʗ}9+u&N'[Hoح2G+*}SxNb|ƧnXzVjeZ +ZFktĥf1enEzq:}rufd7;+XX"Փ՘MduUΦ/IV2OVjZY d5(P$+DV(UIVB'Y "AduKYM "+tq\)G,dY 8:j!Zt:DVNZtw5dtWׅqd zZDVY=uUgd5vtE!d=a* fu GVVX֒Uq!UVj=σu ֯i[;޽q ZcmqZ[lk k#at)  -!#"$+%&'()*,./0123Root Entry F1"4!Data WordDocument.$ObjectPoolv41"4_1166350801 Fv4v4Ole CompObj_ObjInfo  !"#$%&'()*+,-./0123456789:;<=>?@ABCDEFGHILMNOPQRTUVWYZ[\]^_`abcdefghijklmnopqrstuvwxyz{|}~ FISIS/Draw Sketch ISISServer ISISServer9q@OMeaXY Ariald 0a! D@JDN%! Dn8DC% '! plDNJDC% '(! D9DOle10Native Ole10ItemName _1174661865 Fv4v4Ole C % '! D%qnDC!% '! ]WD27DC"% ' ! DIDO#% ' (! =.D DC$% ' ! D@ODC%% ' ! mDD#Br&% ' ! DCC'% ' ! "DroDC(% '! QDyhDC)% '! zD DC*% '(NONE FISIS/Draw Sketch ISISServer ISISServer9qCompObj _ObjInfoOle10Native u Ole10ItemNameJ q @OMeaXY Ariald 0(a! DQDN%! D.?DC% '! plDNQDC% '! cD?DC% '(*!  D RDC% '*! 6DUvDC% ' (*! D\DC% ' *! DBuDC% ' (* ' * ' '! `D>DC% '! 2DPDC% '(! D >DC% '! E~PDC% '(! D8@uDC % '! >FD˃DO!% '(! DaDC"% '! w E6e>DC$% '! DLDC6% '!! "DtD#Br7% '#! DDC8% '%! EyD-jDOMe<<%a '! EyD-jDO<! 7)ZD^DC= '" 4OMe6=! D@vDC>% 0(a! OEQDN%%! ¯GE.?DC&% '! 8?ENQDC'% '! 27E?DC(% '(*! 60E RDC)% '*! |K0EUvDC*% ' (*! :8E\DC+% ' *! @EBuDC,% ' (* ' * ' '! `WE>DC-% '! `I_EPDC.% '(! `gE >DC0% '! nE~PDC1% '(! OE8@uDC2% '! GE˃DO3% '(! }WEaDC4% '! nE~tDC5% '! ӊWELDC9% '!! `A_EtD#Br:% '#! 0_EDC;% '%! `(E-jDOMe<=%a '! `(E-jDO=! O E^DC> '" 4OMe6=! 00E@vDC?% 0 + r} tph||ArialAriald+NONEOh+'0 $0 P \ ht|Single pure compoundAndrew James ClarkNormal1TableX SummaryInformation(KDocumentSummaryInformation8S@CompObjqAndrew James Clark1Microsoft Office Word@Ik@F@&S%!q՜.+,0 hp  University of TV ' Single pure compound Title@`@ MmNormalCJ_HaJmH sH tH DA@D Default Paragraph FontRi@R  Table Normal4 l4a (k@(No ListHP`H Mm Body Text 2$dha$ 56aJ$STlmJK0000000000000006$$ $ $ Thj::KTK>HMm@TTTT@PP P PPUnknownGz Times New Roman5Symbol3& z Arial"1hᆙ!q !q !r4 2QHX)?Mm2Single pure compoundAndrew James ClarkAndrew James Clark  FMicrosoft Office Word Document MSWordDocWord.Document.89q